Galvanic process - fasteners with electroplated coatings (according to ISO 4042)

Galvanizing – Passivation. Galvanizing followed by passivation of fasteners is a procedure which has proven itself in terms of both corrosion resistance and appearance. We can offer you an extensive assortment from our range in stock.  
 
Chromating and/or passivation after-treatment. Is a process for generating a chromating and/or passivation coating by treatment with a solution containing a hexavalent chromium compound (chromating) or trivalent chromium compound (passivating). This after-treatment is carried out immediately after galvanizing by brief immersion into chromic acid solutions. The chromating and/ or passivation process increases corrosion resistance and prevents tarnishing and discolorations of the zinc coating. The protective effect of the layer of chromate differs with the different types of procedure (see the table!).
 
New developments in processes involving chromium(VI)-free coatings offering the same or similar protective effects purred onwards by environmental regulations due to EU Directives 2000/53/EC (ELV) und 2002/95/EC (RoHS). Until now normal practice has been to use galvanic zinc coatings (ISO4042) with chromate treatment based on chromium (VI) for the corrosion protection of fasteners. The new surface treatments based on chromium (VI) – free systems usually require a more complex process control and where necessary additional cover layers, since the «self-healing effect» is missing. Long-term experience gained under working conditions is largely not available and such experience is also influenced by specific conditions such as handling, transport and feeder devices. Consequently it is recommended that a review be made through the adjustment for the different operating conditions met in practice.
Types of prodecure used for the passivation of electroplated zinc coatings

Protective effect of zinc coatings with passivation under conditions of salt spray testing to ISO 9227 (DIN 50021 SS).

Types of procedure used for the passivation of electroplated zinc coatings

Reduction of the risk of hydrogen embrittlement (ISO 4042)

There is a risk of failure due to hydrogen embrittlement in galvanically finished fasteners which are under tensile stress and which are made from steels with tensile strengths of Rm≥ 1000 N/mm², corresponding to ≥ 320 HV.

Heat treatment (tempering) of the parts, e.g. after the acid pickling or metal coating process, will reduce the risk of breakage. However it cannot be guaranteed that the risk of hydrogen embrittlement will be removed completely. If the risk of hydrogen embrittlement must be reduced, then other coating procedures should be considered.

Alternative methods of corrosion protection or coating should therefore be selected for parts which are important to safety, alternatives such as anorganic zinc coating, mechanical galvanization or a switch to rust- and acid-resistant steels.

Where the method of fabrication allows, fasteners in classes≥ 10.9 (≥ HV320) are provided with an anorganic zinc coating or are mechanically galvanized. The user of the fasteners knows the purposes and requirements for which the fasteners are to be used and he must specify the appropriate type of surface treatment!

Possible tolerance adjustments for surface coatings ISO 10684 (hot galvanization)
Possible tolerance adjustments for surface coatings
Measuring points for coating thickness
Measuring points for coating thickness
Further galvanic coating processes
Process Details
Nickel-Plating Nickel-plating is decorative and provides effective corrosion protection. A hard coating, used in the electrical appliance and telecommunications industries. No coating abrasion occurs, especially with screws. Improves protection against impregnation, see table below.
Veralisation (Thick layer nickel plating)

Is a galvanic (electrochemical) nickel coating ideally suited for workpieces subjected to heavy loads.
–> Application of a tough and non-hard nickel layer.

Chromium-plating Usually following nickel-plating. Coating thickness about 0,5 – 1,0 μm.
Chromium is decorative, enhances resistance to tarnishing and also serves as corrosion protection.
Bright chromium-plated: high brightness finish.
Matt chromium-plated: matt lustre (silk finish).
Drum chromium plating not possible.
Creates a hard surface with good wear and sliding properties.
Brass-plating Brass plating is mainly applied for decorative purposes. In addition, steel components are brass-plated in order to improve the adhesion of rubber to steel.
Copper-plating As primer prior to nickel-plating, chrome-plating, and silver-plating as needed. Used for decorative purposes.
Silver-plating Silver-plating is employed for decorative and technical applications.
Tin-plating Tin-plating is carried out mainly to permit or improve soldering (soft-solder).
Simultaneously serves as corrosion protection. Subsequent heat treatment not possible.
Anodizing When aluminum is anodized (electrolytic oxidation), a coating which provides corrosion protection is produced – also prevents tarnishing. Practically any color can be produced for decorative purposes in a downstream coloring process.
Zinc / iron alloy coating
Is a galvanic coating process which uses an electrolyte that precipitates a zinc-iron alloy on a metallic component. Following the coating a Cr(VI)-free black passivation and black sealing is applied. It is mainly used when a cosmetic black surface is desired.
Zinc / nickel alloy coating
The zinc-nickel coatings have a deposition of approximately 12 – 16 % share of nickel during the galvanization. Here one has the possibility to use a transparent or black passivation and to optimize by a sealing. This coating is mainly used because of its good corrosion protection in use.
Further surface treatments
Process Details 
Hot-dip galvanizing Immersion in molten zinc with a temp. of about 440 °C to 470 °C. Thickness of coating not less than 40 μm.
Finish dull and rough. Color change possible after a certain time.
Very good corrosion protection. Can be used for thread parts from M8. Threads need to be over or undercut to assure proper thread mating.
Zinc flake coatings
Geomet®
Delta-Tone® / Delta-Protekt®
Zinc flake coatings are excellent for high strength components with tensile strength of Rm ≥ 1000 N/mm2
(Property class ≥ 10.9, Hardness ≥ 320 HV).
This process practically eliminates the possibility of hydrogen embrittlement. Temperature resistant 300 °C.
Can be applied to size M4 and up.
Mechanical plating Mechanical / chemical process. The degreased parts are placed in a drum with powdered zinc and glass pellets.
The pellets serve to transfer the zinc powder to the surface to be treated.
Black oxidizing of
Stainless steel
Chemical process in hot hydroxide solution.
For decorative purposes.
Black oxidizing Chemical process, bath temperature about 140 °C.
For decorative purposes. Temporary corrosion protection only.
Phosphate
(bonderizing, parkerizing,
atramentizing)
Only slight corrosion protection. Good undercoat for painting. Grey to grey-black appearance.
Better corrosion protection oiled.
Waterproofing / sealing Particularly with nickel-plated parts, subsequent treatment in dewatering fluid with the addition of wax may seal the micropores with wax. Significantly improves the corrosion resistance.
The wax film is dry and invisible.
Baking Following electrolytic or pickling treatment, high tensile strength steel parts (from Rm ≥ 1000 N/mm2, corresponding to ≥ 320 HV) can become brittle due to hydrogen absorption (hydrogen embrittlement). This embrittlement increases for components with small cross sections. Part of the hydrogen can be eliminated by baking between 180 °C and 230 °C (below tempering temperature). Experience indicates that this is not guaranteed 100%.
Baking for >4 hrs must immediately be carried out after pickling and after galvanic treatment.
Sealing Sealing is applied to the component using an immersion process after galvanization and passivation. Sealing increases corrosion resistance.
Tribological coating1)
(Solid film lubricants)
These coatings provide a friction reducing and wear resistant film.
Reduce galling tendency.
Waxing Provide a lubrication layer, reduces driving torque of thread-forming screws.
WIROX® Is a galvanic coating with zinc, average thickness at least 8 μm. The corrosion protection is more than 20 times higher, compared with plain galvanizing. The coating is resistant to abrasion, mechanical loads and is characterized by an exceptionally high corrosion resistance.
YELLOX® Is a galvanic coating with zinc, average thickness at least 4 μm. The corrosion protection is more than 6 times higher, compared with plain galvanizing. Screw applications with yellowish appearance are guaranteed in the future.
GreenTec® Is a galvanic coating, thickness about 5 μm, zinc-nickel-based and provides hard, wear-resistant coating with very high corrosion resistance.

1)
Bossard ecosyn®-lubric tribological dry coating is a non-electrolytically applied, thin layered coating with integrated lubricating properties and additional corrosion protection. The coating consists of a composition of fluoropolymers and organic submicroscopic solid lubricant particles, which are dispersed in carefully selected synthetic resin blends and solvents. The AFC coating (Anti-Friction-Coating) creates a smooth film, which balances all unevenness of the surface thereby optimising friction under extreme loads and working conditions. The synthectic resin in turn ensures better corrosion protection.

Coating thicknesses for parts with external thread

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